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CBSE Class XII Chemistry Part 1 Formula & Constant Reference

62+ formula cards with KaTeX-rendered equations, units, traps, deterministic tools, and metadata-only NCERT locator context. Free, no login needed.

Chapter-linked constants

CBSE Class XII Chemistry formula cockpit

The launch formula layer connects every high-risk expression to its chapter, outcome, constants, common trap, deterministic tool, and answer-masked practice path. Official sources remain locator metadata; this page does not copy textbook passages.

CBSE-12-CHEM-CH1

Concentration unit check

Molarity, molality, mole fraction

Solutions
Source locator: NCERT Class XII Chemistry Part 1 > Chapter 1 > formulas and constants locator metadata. This is coordinate context only, not copied textbook explanation.

Constants and units

  • - Volume must be in litres
  • - Solvent mass must be in kg
  • - Mole fractions sum to 1

Common trap

Do not use solution mass where solvent mass is required for molality.

CBSE-12-CHEM-CH1

Raoult law vapor pressure

Raoult law, partial pressure, and vapor composition

Solutions
Source locator: NCERT Class XII Chemistry Part 1 > Chapter 1 > formulas and constants locator metadata. This is coordinate context only, not copied textbook explanation.

Constants and units

  • - M(CHCl3) = 119.5 g mol^-1
  • - M(CH2Cl2) = 85.0 g mol^-1
  • - Use liquid mole fractions for partial pressures

Common trap

Do not use mass fraction where mole fraction is required.

CBSE-12-CHEM-CH1

Boiling point elevation

Ebullioscopy, molality, and molar mass

Solutions
Source locator: NCERT Class XII Chemistry Part 1 > Chapter 1 > formulas and constants locator metadata. This is coordinate context only, not copied textbook explanation.

Constants and units

  • - Kb(water) = 0.512 K kg mol^-1
  • - m uses kg of solvent
  • - Delta Tb is added to Tb0

Common trap

Do not use solution mass instead of solvent mass.

CBSE-12-CHEM-CH2

Nernst sign and Q setup

Nernst equation and reaction quotient

Electrochemistry
Source locator: NCERT Class XII Chemistry Part 1 > Chapter 2 > electrochemical cells and Nernst locator metadata. This is coordinate context only, not copied textbook explanation.

Constants and units

  • - F = 96485 C mol^-1
  • - R = 8.314 J mol^-1 K^-1
  • - 0.0591 V applies at 298 K

Common trap

A flipped reaction quotient reverses the sign of the correction.

CBSE-12-CHEM-CH2

Kohlrausch law check

Limiting molar conductivity and weak electrolyte dissociation

Electrochemistry
Source locator: NCERT Class XII Chemistry Part 1 > Chapter 2 > electrochemical cells and Nernst locator metadata. This is coordinate context only, not copied textbook explanation.

Constants and units

  • - lambda0(H+) = 349.6 S cm2 mol^-1
  • - lambda0(CH3COO-) = 40.9 S cm2 mol^-1
  • - alpha is dimensionless

Common trap

Do not use measured Lambda_m as Lambda_m0 for weak electrolytes.

CBSE-12-CHEM-CH2

Faraday electrolysis mass

Faraday laws, charge, and deposited mass

Electrochemistry
Source locator: NCERT Class XII Chemistry Part 1 > Chapter 2 > electrochemical cells and Nernst locator metadata. This is coordinate context only, not copied textbook explanation.

Constants and units

  • - F = 96485 C mol^-1
  • - n = electrons in the half-reaction
  • - time must be in seconds

Common trap

Do not forget to divide by electron count n for multivalent ions.

CBSE-12-CHEM-CH3

First-order half-life

Integrated first-order rate law

Chemical Kinetics
Source locator: NCERT Class XII Chemistry Part 1 > Chapter 3 > integrated rate laws locator metadata. This is coordinate context only, not copied textbook explanation.

Constants and units

  • - 2.303 converts ln to log10
  • - 0.693 = ln 2
  • - k has unit s^-1 for first order

Common trap

First-order half-life is independent of starting concentration.

CBSE-12-CHEM-CH4

Spin-only magnetic moment

d-electron count and unpaired electrons

d and f Block Elements
Source locator: NCERT Class XII Chemistry Part 1 > Chapter 4 > d/f-block trends locator metadata. This is coordinate context only, not copied textbook explanation.

Constants and units

  • - n = unpaired electrons
  • - BM = Bohr magneton
  • - Oxidation state fixes d-electron count

Common trap

Count d electrons after removing ns electrons first for transition-metal cations.

CBSE-12-CHEM-CH5

CFT splitting direction

Octahedral/tetrahedral splitting and spin state

Coordination Compounds
Source locator: NCERT Class XII Chemistry Part 1 > Chapter 5 > coordination compounds locator metadata. This is coordinate context only, not copied textbook explanation.

Constants and units

  • - Octahedral: t2g lower, eg higher
  • - Tetrahedral order is inverted
  • - Strong field favours low spin when pairing wins

Common trap

Do not apply octahedral orbital order directly to tetrahedral complexes.

Showing 62 of 62 formulas

Chapter 1: Some Basic Concepts of Chemistry

Class 11

Mole concept
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where: n = moles, m = mass (g), M = molar mass (g/mol), N = number of particles, N_A = 6.022\times 10^{23}

Molarity
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where: Concentration in mol/L. Temperature-dependent (volume changes).

Molality
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where: Concentration in mol/kg. Temperature-independent.

Mole fraction
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where: Dimensionless ratio of moles of A to total moles.

Percentage composition
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where: Mass-based elemental composition of a compound.

Empirical → molecular formula
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where: Molecular formula = (empirical formula)_n.

Chapter 2: Structure of Atom

Class 11

Bohr radius (n-th orbit)
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where: n = principal quantum number, Z = atomic number.

Bohr energy (n-th orbit, H-like)
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where: Energy of the n-th orbit. Negative ⇒ bound state.

Rydberg formula
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where: R_H = 1.097\times 10^{7}\,\text{m}^{-1}; n_2 > n_1.

de Broglie wavelength
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where: h = 6.626\times 10^{-34}\,\text{J·s}.

Heisenberg uncertainty
JEE

where: Position–momentum uncertainty product floor.

Photon energy
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where: c = 3\times 10^{8}\,\text{m/s}.

Chapter 5: States of Matter (Gases & Liquids)

Class 11

Ideal gas equation
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where: R = 0.0821\,\text{L·atm·K}^{-1}\!\text{·mol}^{-1} = 8.314\,\text{J·K}^{-1}\!\text{·mol}^{-1}.

Boyle's Law
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where: Isothermal process.

Charles's Law
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where: Isobaric process. T in Kelvin.

Dalton's Law of Partial Pressures
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where: Mixture of non-reacting gases.

Graham's Law of Diffusion
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where: Rate of effusion ∝ 1/√M at same T, P.

RMS speed
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where: Average kinetic-molecular speed; M in kg/mol.

van der Waals equation
JEE

where: Real-gas correction; a (attraction), b (excluded volume).

Chapter 6: Thermodynamics

Class 11

First Law of Thermodynamics
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where: Sign convention: w = work done ON the system; q = heat absorbed BY system.

Enthalpy definition
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where: \Delta n_g = (n_{\text{gas, products}} - n_{\text{gas, reactants}}).

Hess's Law
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where: Path-independence of state functions.

Gibbs free energy
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where: \Delta G < 0 ⇒ spontaneous at constant T, P.

Gibbs–Helmholtz (equilibrium)
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where: K = thermodynamic equilibrium constant.

Work — isothermal reversible expansion
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where: Ideal gas; reversible isothermal.

Entropy of mixing / phase change
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where: For phase change: \Delta S = \Delta H_{\text{fus/vap}}/T.

Chapter 7: Equilibrium

Class 11

K_c – K_p relation
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where: \Delta n_g = moles gaseous products – moles gaseous reactants.

Reaction quotient
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where: Q < K → forward; Q = K → equilibrium; Q > K → reverse.

Ostwald's dilution law (weak electrolyte)
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where: α = degree of dissociation, c = concentration.

pH and water autoionization
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where: pH + pOH = 14 at 25 °C.

Henderson–Hasselbalch
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where: Buffer solution pH; valid when α small.

Solubility product
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where: s = molar solubility.

Chapter 8: Redox Reactions

Class 11

Equivalent mass
JEE

where: n = number of electrons transferred (or H⁺/OH⁻ for acid–base).

Normality–molarity
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where: n = n-factor of the species.

Titration formula
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where: At endpoint of acid–base or redox titration.

Chapter 2: Solutions

Class 12

Raoult's Law (ideal)
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where: Vapour pressure of an ideal binary solution.

Relative lowering of vapour pressure
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where: Colligative property.

Boiling point elevation
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where: K_b = ebullioscopic constant; i = van 't Hoff factor.

Freezing point depression
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where: K_f = cryoscopic constant.

Osmotic pressure
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where: C = molar concentration; T in Kelvin.

van 't Hoff factor
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where: n = number of particles formed; α = degree.

Chapter 3: Electrochemistry

Class 12

Standard cell EMF
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where: Both half-cells in reduction-potential convention.

Nernst equation
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where: n = electrons transferred; Q = reaction quotient.

Gibbs–EMF relation
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where: F = 96485 C/mol; n = electrons transferred.

Faraday's First Law
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where: Mass deposited at electrode; Z = electrochemical equivalent.

Conductivity ↔ molar conductivity
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where: κ in S/cm; C in mol/L; Λ_m in S·cm²/mol.

Kohlrausch's Law (limiting molar conductivity)
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where: Independent migration of ions at infinite dilution.

Chapter 4: Chemical Kinetics

Class 12

Rate law (general)
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where: Order = x+y; determined experimentally.

Integrated zero-order rate
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where: k has units of mol·L⁻¹·s⁻¹.

Integrated first-order rate
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where: Half-life independent of initial concentration.

Arrhenius equation
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where: A = pre-exponential factor; E_a = activation energy.

Chapter 1: The Solid State

Class 12

Density of a unit cell
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where: Z = atoms/unit cell; a = edge length; M = molar mass.

Packing efficiency
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where: FCC/CCP = 74%, BCC = 68%, SC = 52.4%.

Edge–radius (FCC)
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where: Atoms touch along the face diagonal.

Edge–radius (BCC)
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where: Atoms touch along the body diagonal.

Chapter 5: Surface Chemistry

Class 12

Freundlich adsorption isotherm
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where: Empirical; log–log plot is linear.

Langmuir isotherm
JEE

where: Monolayer adsorption; saturates at high P.

Chapter 9: Coordination Compounds

Class 12

Effective Atomic Number (EAN)
JEE

where: CN = coordination number. Sidgwick's rule.

Magnetic moment (spin-only)
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where: n = unpaired electrons.

CFSE (octahedral)
JEE

where: Δ_o = octahedral field splitting energy.

Chapter 10: Haloalkanes & Haloarenes

Class 12

S_N1 vs S_N2 (qualitative rate law)
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where: S_N1: 3°>2°>1°·CH₃; S_N2: opposite order.

Chapter 14: Biomolecules

Class 12

Specific rotation
JEE

where: l = path length (dm); c = concentration (g/mL).

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CBSE Class XII Chemistry Part 1 Formula & Constant Reference

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